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Crystal structure of bis{μ(2)-[(2-iminocyclopentylidene)methylidene]azanido-κ(2) N:N′}bis[(η(5)-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate
The title compound, [Zr(2)(C(10)H(15))(4)(C(6)H(6)N(2))(2)]·C(6)H(14), was obtained by the stoichiometric reaction of adiponitrile with [Zr(C(10)H(15))(2)(η(2)-Me(3)SiC(2)SiMe(3))]. Intramolecular nitrile–nitrile couplings and deprotonation of the substrate produced the (1-imino-2-enimino)cyclop...
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| Publicado no: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Principais autores: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Union of Crystallography
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4719842/ https://ncbi.nlm.nih.gov/pubmed/26870433 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015021234 |
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