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Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis()

An expanded family of ruthenium metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands is reported. These catalysts exhibited exceptional activity in the ethenolysis of the seed oil derivative methyl oleate. In many cases, TONs >100,000 were achieved, at only 3 ppm catalyst loadin...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Marx, Vanessa M., Sullivan, Alexandra H., Melaimi, Mohand, Virgil, Scott C., Keitz, Benjamin K., Weinberger, David S., Bertrand, Guy, Grubbs, Robert H.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2014
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4713124/
https://ncbi.nlm.nih.gov/pubmed/25522160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201410797
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