Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis()

An expanded family of ruthenium metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands is reported. These catalysts exhibited exceptional activity in the ethenolysis of the seed oil derivative methyl oleate. In many cases, TONs >100,000 were achieved, at only 3 ppm catalyst loadin...

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發表在:Angew Chem Int Ed Engl
Main Authors: Marx, Vanessa M., Sullivan, Alexandra H., Melaimi, Mohand, Virgil, Scott C., Keitz, Benjamin K., Weinberger, David S., Bertrand, Guy, Grubbs, Robert H.
格式: Artigo
語言:Inglês
出版: 2014
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4713124/
https://ncbi.nlm.nih.gov/pubmed/25522160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201410797
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