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Competition H(D) Kinetic Isotope Effects in the Autoxidation of Hydrocarbons

Hydrogen atom transfer is central to many important radical chain sequences. We report here a method for determination of both the primary and secondary isotope effects for symmetrical substrates by the use of NMR. Intramolecular competition reactions were carried out on substrates having an increas...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Muchalski, Hubert, Levonyak, Alexander J., Xu, Libin, Ingold, Keith U., Porter, Ned A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4710063/
https://ncbi.nlm.nih.gov/pubmed/25533605
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511434j
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