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Competition H(D) Kinetic Isotope Effects in the Autoxidation of Hydrocarbons
Hydrogen atom transfer is central to many important radical chain sequences. We report here a method for determination of both the primary and secondary isotope effects for symmetrical substrates by the use of NMR. Intramolecular competition reactions were carried out on substrates having an increas...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4710063/ https://ncbi.nlm.nih.gov/pubmed/25533605 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511434j |
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