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Dissecting Proton Delocalization in an Enzyme’s Hydrogen Bond Network with Unnatural Amino Acids

Extended hydrogen bond networks are a common structural motif of enzymes. A recent analysis proposed quantum delocalization of protons as a feature present in the hydrogen bond network spanning a triad of tyrosines (Y(16), Y(32), and Y(57)) in the active site of ketosteroid isomerase (KSI), contribu...

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Detalhes bibliográficos
Publicado no:Biochemistry
Main Authors: Wu, Yufan, Fried, Stephen D., Boxer, Steven G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4692369/
https://ncbi.nlm.nih.gov/pubmed/26571340
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b00958
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