Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

Asymmetric amplification during self-replication is a key feature that is used to explain the origin of homochirality. Asymmetric autocatalysis of pyrimidyl alkanol in the asymmetric addition of diisopropylzinc to pyrimidine-5-carbaldehyde is a unique example of this phenomenon. Crystallization of z...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Matsumoto, Arimasa, Abe, Takaaki, Hara, Atsushi, Tobita, Takayuki, Sasagawa, Taisuke, Kawasaki, Tsuneomi, Soai, Kenso
Formáid: Artigo
Teanga:Inglês
Foilsithe: WILEY-VCH Verlag 2015
Ábhair:
Communications
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4691336/
https://ncbi.nlm.nih.gov/pubmed/26494200
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508036
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