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Efficient Synthesis of β-CF(3)/SCF(3) Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols
The first copper-catalyzed ring-opening electrophilic trifluoromethylation and trifluoromethylthiolation of cyclopropanols to form C(sp3)-CF(3) and C(sp3)-SCF(3) bonds have been realized. These transformations are efficient for the synthesis of β-CF(3) and β-SCF(3) substituted carbonyl compounds tha...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4690544/ https://ncbi.nlm.nih.gov/pubmed/25885795 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00782 |
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