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An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols
A novel copper-catalyzed electrophilic amination of cyclopropanols with O-benzoyl-N,-N-dialkylhydroxylamines to synthesize various β-aminoketones via a sequence of C-C bond cleavage and C(sp3)-N bond formation is reported. The reaction conditions are mild and tolerate a wide range of functional grou...
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| Publicado no: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4690534/ https://ncbi.nlm.nih.gov/pubmed/25885943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00828 |
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