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Asymmetric intramolecular α-cyclopropanation of aldehydes using a donor/acceptor carbene mimetic
Enantioselective α-alkylation of carbonyl is considered as one of the most important processes for asymmetric synthesis. Common alkylation agents, that is, alkyl halides, are notorious substrates for both Lewis acids and organocatalysts. Recently, olefins emerged as a benign alkylating species via p...
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| Publicado no: | Nat Commun |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4686670/ https://ncbi.nlm.nih.gov/pubmed/26644194 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms10041 |
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