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Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentin A, B, and C
The direct α-vinylation of carbonyl compounds that forms a quaternary stereocenter is a challenging transformation. We discovered that δ-oxocarboxylic acids can serve as masked vinyl compounds and be unveiled by palladium-catalyzed decarbonylative dehydration. The carboxylic acids are readily availa...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4686263/ https://ncbi.nlm.nih.gov/pubmed/26230413 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505161 |
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