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Ruthenium-Catalyzed meta-Selective C—H Bromination

The first example of a transition-metal-catalyzed, meta-selective C–H bromination procedure is reported. In the presence of catalytic [{Ru(p-cymene)Cl(2)}(2)], tetrabutylammonium tribromide can be used to functionalize the meta C–H bond of 2-phenylpyridine derivatives, thus affording difficult to ac...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Teskey, Christopher J, Lui, Andrew Y W, Greaney, Michael F
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4678425/
https://ncbi.nlm.nih.gov/pubmed/26288217
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504390
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