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Ring expansions of acyloxy nitroso compounds
Treatment of cyclopentanone and cyclobutanone-derived oximes with lead (IV) tetraacetate gives the bright blue acyloxy nitroso compounds, which upon basic hydrolysis yields the ring expansion product cyclic hydroxamic acids in 12–81% yield. Reactions of substituted cyclopentanones provide ring expan...
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4671303/ https://ncbi.nlm.nih.gov/pubmed/26663984 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.09.002 |
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