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Dearomative Indole (3 + 2) Reactions with Azaoxyallyl Cations – New Method for the Synthesis of Pyrroloindolines

[Image: see text] Herein, we report the first examples of the synthesis of pyrroloindolines by means of (3 + 2) dearomative annulation reactions between 3-substituted indoles and highly reactive azaoxyallyl cations. Computational studies using density functional theory (DFT) (B3LYP-D3/6-311G**++) su...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: DiPoto, Maria C., Hughes, Russell P., Wu, Jimmy
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2015
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4669536/
https://ncbi.nlm.nih.gov/pubmed/26562355
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10221
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