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Cation-cation clusters in ionic liquids: Cooperative hydrogen bonding overcomes like-charge repulsion
Direct spectroscopic evidence for H-bonding between like-charged ions is reported for the ionic liquid, 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate. New infrared bands in the OH frequency range appear at low temperatures indicating the formation of H-bonded cation-cation clusters simila...
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| Опубликовано в: : | Sci Rep |
|---|---|
| Главные авторы: | , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Nature Publishing Group
2015
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4667241/ https://ncbi.nlm.nih.gov/pubmed/26626928 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep17505 |
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