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Cation-cation clusters in ionic liquids: Cooperative hydrogen bonding overcomes like-charge repulsion

Direct spectroscopic evidence for H-bonding between like-charged ions is reported for the ionic liquid, 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate. New infrared bands in the OH frequency range appear at low temperatures indicating the formation of H-bonded cation-cation clusters simila...

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書目詳細資料
發表在:Sci Rep
Main Authors: Knorr, Anne, Ludwig, Ralf
格式: Artigo
語言:Inglês
出版: Nature Publishing Group 2015
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4667241/
https://ncbi.nlm.nih.gov/pubmed/26626928
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep17505
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