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Enhanced Diastereoselectivity in β-Mannopyranosylation through the Use of Sterically Minimal Propargyl Ether Protecting Groups
2-O-Propargyl ethers are shown to be advantageous in the 4,6-O-benzylidene acetal directed β-mannosylation reaction. The effect is most pronounced when the 3-O-protecting group is bulky silyl ether or a glycosidic bond, however, even with a 3-O-benzyl ether the use of a 2-O-propargyl ether results i...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4664462/ https://ncbi.nlm.nih.gov/pubmed/16599600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0526789 |
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