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Application of the 4-Trifluoromethylbenzenepropargyl Ether Group as an Unhindered, Electron Deficient Protecting Group for Stereoselective Glycosylation

[Image: see text] 4-Trifluoromethylbenzenepropargyl ethers are stable and sterically minimal alcohol protecting groups that are readily cleaved in a single step by exposure to lithium naphthalenide. In conjunction with the 4,6-O-benzylidene protecting group, glycosylation reactions of 2-O-4-trifluor...

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Autores principales: Crich, David, Karatholuvhu, Maheswaran S.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2742709/
https://ncbi.nlm.nih.gov/pubmed/18529028
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo7023398
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