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Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Three new Au(I) complexes of the formula [Au(NHC)(NTf(2))] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the ‘ITent’ (‘Tent’ for ‘tentacular’) family of NHC derivatives. The effect of these ligan...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Collado, Alba, Patrick, Scott R, Gasperini, Danila, Meiries, Sebastien, Nolan, Steven P
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4661005/
https://ncbi.nlm.nih.gov/pubmed/26664600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.196
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