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Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones
The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.
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| Publicado no: | Sci Rep |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4655356/ https://ncbi.nlm.nih.gov/pubmed/26592555 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep16886 |
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