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Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones

The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Sci Rep
Prif Awduron: Ceban, Victor, Tauchman, Jiří, Meazza, Marta, Gallagher, Greg, Light, Mark E., Gergelitsová, Ivana, Veselý, Jan, Rios, Ramon
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Nature Publishing Group 2015
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4655356/
https://ncbi.nlm.nih.gov/pubmed/26592555
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep16886
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