Photoisomerization mechanism of the rhodopsin chromophore: picosecond photolysis of pigment containing 11-cis-locked eight-membered ring retinal.

The primary photochemical event in rhodopsin is an 11-cis to 11-trans photoisomerization of its retinylidene chromophore to form the primary intermediate photorhodopsin. Earlier picosecond studies have shown that no intermediate is formed when the retinal 11-ene is fixed through a bridging five-memb...

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Bibliografiske detaljer
Main Authors: Mizukami, T, Kandori, H, Shichida, Y, Chen, A H, Derguini, F, Caldwell, C G, Biffe, C F, Nakanishi, K, Yoshizawa, T
Format: Artigo
Sprog:Inglês
Udgivet: 1993
Fag:
Research Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC46448/
https://ncbi.nlm.nih.gov/pubmed/8483923
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