Turning Cucurbit[8]uril into a Supramolecular Nanoreactor for Asymmetric Catalysis

Chiral macromolecules have been widely used as synthetic pockets to mimic natural enzymes and promote asymmetric reactions. An achiral host, cucurbit[8]uril (CB[8]), was used for an asymmetric Lewis acid catalyzed Diels–Alder reaction. We achieved a remarkable increase in enantioselectivity and a la...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Zheng, Lifei, Sonzini, Silvia, Ambarwati, Masyitha, Rosta, Edina, Scherman, Oren A, Herrmann, Andreas
Materialtyp: Artigo
Språk:Inglês
Publicerad: WILEY-VCH Verlag 2015
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4643185/
https://ncbi.nlm.nih.gov/pubmed/26383272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505628
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