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Turning Cucurbit[8]uril into a Supramolecular Nanoreactor for Asymmetric Catalysis
Chiral macromolecules have been widely used as synthetic pockets to mimic natural enzymes and promote asymmetric reactions. An achiral host, cucurbit[8]uril (CB[8]), was used for an asymmetric Lewis acid catalyzed Diels–Alder reaction. We achieved a remarkable increase in enantioselectivity and a la...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
WILEY-VCH Verlag
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4643185/ https://ncbi.nlm.nih.gov/pubmed/26383272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505628 |
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