Coordination Polymer Flexibility Leads to Polymorphism and Enables a Crystalline Solid–Vapour Reaction: A Multi-technique Mechanistic Study

Despite an absence of conventional porosity, the 1D coordination polymer [Ag(4)(O(2)C(CF(2))(2)CF(3))(4)(TMP)(3)] (1; TMP=tetramethylpyrazine) can absorb small alcohols from the vapour phase, which insert into Ag–O bonds to yield coordination polymers [Ag(4)(O(2)C(CF(2))(2)CF(3))(4)(TMP)(3)(ROH)(2)]...

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Publicado no:Chemistry
Main Authors: Vitórica-Yrezábal, Iñigo J, Libri, Stefano, Loader, Jason R, Mínguez Espallargas, Guillermo, Hippler, Michael, Fletcher, Ashleigh J, Thompson, Stephen P, Warren, John E, Musumeci, Daniele, Ward, Michael D, Brammer, Lee
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4641464/
https://ncbi.nlm.nih.gov/pubmed/25962844
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201500514
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