Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

[Image: see text] The first general method for the enantioselective construction of all-carbon quaternary centers on cyclopentanones by enantioselective palladium-catalyzed decarboxylative allylic alkylation is described. Employing the electronically modified (S)-(p-CF(3))(3)-t-BuPHOX ligand, α-quat...

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Julkaisussa:Org Lett
Päätekijät: Craig, Robert A., Loskot, Steven A., Mohr, Justin T., Behenna, Douglas C., Harned, Andrew M., Stoltz, Brian M.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: American Chemical Society 2015
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4640231/
https://ncbi.nlm.nih.gov/pubmed/26501770
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02376
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