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Dependence of Vibronic Coupling on Molecular Geometry and Environment: Bridging Hydrogen Atom Transfer and Electron–Proton Transfer

[Image: see text] The rate constants for typical concerted proton-coupled electron transfer (PCET) reactions depend on the vibronic coupling between the diabatic reactant and product states. The form of the vibronic coupling is different for electronically adiabatic and nonadiabatic reactions, which...

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Dades bibliogràfiques
Publicat a:J Am Chem Soc
Autors principals: Harshan, Aparna Karippara, Yu, Tao, Soudackov, Alexander V., Hammes-Schiffer, Sharon
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2015
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4629534/
https://ncbi.nlm.nih.gov/pubmed/26412613
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07327
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