A Mixed-Valence Octanuclear Iron-Oxo Pyrazolate: Assessment of Electronic Delocalization by Structural and Spectroscopic Analysis

A formally Fe(III)(7)Fe(II) complex, containing an inner Fe(4)O(4)-cubane and four peripheral Fe-centers, is derived from the one-electron reduction of its Fe(III)(8) precursor. Spectroscopic analysis of the former reveals that the redox activity of this Fe(8)-system is confined within its cubane co...

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Bibliografiset tiedot
Julkaisussa:Inorg Chem
Päätekijät: Chakraborty, Indranil, Baran, Peter, Sanakis, Yiannis, Simopoulos, Athanassios, Fachini, Esteban, Raptis, Raphael G.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2008
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Article
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4617381/
https://ncbi.nlm.nih.gov/pubmed/18998629
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic801459s
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