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A Mixed-Valence Octanuclear Iron-Oxo Pyrazolate: Assessment of Electronic Delocalization by Structural and Spectroscopic Analysis
A formally Fe(III)(7)Fe(II) complex, containing an inner Fe(4)O(4)-cubane and four peripheral Fe-centers, is derived from the one-electron reduction of its Fe(III)(8) precursor. Spectroscopic analysis of the former reveals that the redox activity of this Fe(8)-system is confined within its cubane co...
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| 發表在: | Inorg Chem |
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| Main Authors: | , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2008
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4617381/ https://ncbi.nlm.nih.gov/pubmed/18998629 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic801459s |
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