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Catalytic arylsulfonyl radical-triggered 1,5-enyne-bicyclizations and hydrosulfonylation of α,β-conjugates
A catalytic bicyclization reaction of 1,5-enynes anchored by α,β-conjugates with arylsulfonyl radicals generated in situ from sulfonyl hydrazides has been established using TBAI (20 mol%) and Cu(OAc)(2) (5 mol%) as co-catalysts under convenient conditions. In addition, the use of benzoyl peroxide (B...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4608173/ https://ncbi.nlm.nih.gov/pubmed/26568814 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02343b |
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