Catalytic arylsulfonyl radical-triggered 1,5-enyne-bicyclizations and hydrosulfonylation of α,β-conjugates

A catalytic bicyclization reaction of 1,5-enynes anchored by α,β-conjugates with arylsulfonyl radicals generated in situ from sulfonyl hydrazides has been established using TBAI (20 mol%) and Cu(OAc)(2) (5 mol%) as co-catalysts under convenient conditions. In addition, the use of benzoyl peroxide (B...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Chen, Zhen-Zhen, Liu, Shuai, Hao, Wen-Juan, Xu, Ge, Wu, Shuo, Miao, Jiao-Na, Jiang, Bo, Wang, Shu-Liang, Tu, Shu-Jiang, Li, Guigen
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4608173/
https://ncbi.nlm.nih.gov/pubmed/26568814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02343b
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