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Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand

A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined and all delivered high enantioselectivity...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Yu, Zhiyong, Eno, Meredith S., Annis, Alexandra H., Morken, James P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4608024/
https://ncbi.nlm.nih.gov/pubmed/26091063
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b01421
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