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Transition-metal free umpolung carbon-nitrogen vs. carbon-chlorine bond formation
The formation of carbon-nitrogen (C–N) bonds via an umpolung substitution reaction has been achieved at −78 °C without the need for catalysts, ligands, or additives. The scope is limited to aryl Grignard reagents with N-chloroamines. The findings in this manuscript serve as a reference point for all...
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4604600/ https://ncbi.nlm.nih.gov/pubmed/26478603 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.08.053 |
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