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Transition-metal free umpolung carbon-nitrogen vs. carbon-chlorine bond formation

The formation of carbon-nitrogen (C–N) bonds via an umpolung substitution reaction has been achieved at −78 °C without the need for catalysts, ligands, or additives. The scope is limited to aryl Grignard reagents with N-chloroamines. The findings in this manuscript serve as a reference point for all...

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Publicat a:Tetrahedron Lett
Autors principals: Sirois, John J., DeBoef, Brenton
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4604600/
https://ncbi.nlm.nih.gov/pubmed/26478603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.08.053
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