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Strong frequency dependence of vibrational relaxation in bulk and surface water reveals sub-picosecond structural heterogeneity

Because of strong hydrogen bonding in liquid water, intermolecular interactions between water molecules are highly delocalized. Previous two-dimensional infrared spectroscopy experiments have indicated that this delocalization smears out the structural heterogeneity of neat H(2)O. Here we report on...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: van der Post, Sietse T., Hsieh, Cho-Shuen, Okuno, Masanari, Nagata, Yuki, Bakker, Huib J., Bonn, Mischa, Hunger, Johannes
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Pub. Group 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4595750/
https://ncbi.nlm.nih.gov/pubmed/26382651
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms9384
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