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Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study

Gold(I)-catalysed direct allylic etherifications have been successfully carried out with chirality transfer to yield enantioenriched, γ-substituted secondary allylic ethers. Our investigations include a full substrate-scope screen to ascertain substituent effects on the regioselectivity, stereoselec...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Barker, Graeme, Johnson, David G, Young, Paul C, Macgregor, Stuart A, Lee, Ai-Lan
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4586480/
https://ncbi.nlm.nih.gov/pubmed/26248980
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201501607
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