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Spiro annulation of cage polycycles via Grignard reaction and ring-closing metathesis as key steps
A simple synthetic strategy to C(2)-symmetric bis-spiro-pyrano cage compound 7 involving ring-closing metathesis is reported. The hexacyclic dione 10 was prepared from simple and readily available starting materials such as 1,4-naphthoquinone and cyclopentadiene. The synthesis of an unprecedented oc...
Shranjeno v:
| izdano v: | Beilstein J Org Chem |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Beilstein-Institut
2015
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4578432/ https://ncbi.nlm.nih.gov/pubmed/26425191 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.147 |
| Oznake: |
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