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Tandem Z-selective cross metathesis – dihydroxylation for the synthesis of anti-1,2-diols()

A stereoselective synthesis of anti-1,2-diols has been developed using a multitasking Ru-catalyst in an assisted tandem catalysis protocol. A cyclometalated ruthenium complex catalyzes first a Z-selective cross metathesis of two terminal olefins followed by a stereospecific dihydroxylation. Both ste...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Dornan, Peter K., Wickens, Zachary K., Grubbs, Robert H.
Format: Artigo
Idioma:Inglês
Publicat: 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4547607/
https://ncbi.nlm.nih.gov/pubmed/25914354
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501505
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