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Tandem Z-selective cross metathesis – dihydroxylation for the synthesis of anti-1,2-diols()
A stereoselective synthesis of anti-1,2-diols has been developed using a multitasking Ru-catalyst in an assisted tandem catalysis protocol. A cyclometalated ruthenium complex catalyzes first a Z-selective cross metathesis of two terminal olefins followed by a stereospecific dihydroxylation. Both ste...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4547607/ https://ncbi.nlm.nih.gov/pubmed/25914354 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501505 |
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