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Organo-Manganese η(2)-Auxiliary Directed Reactions: A Diastereoselective Approach to 2,3-Allenols
[Image: see text] Propargyl aldehydes underwent isomerization to allenyl aldehydes under mildly basic conditions when complexed to an organo-manganese auxiliary using methylcyclopentadienyl manganese tricarbonyl (MMT). This traceless auxiliary magnifies the axial chirality of the allene moiety, allo...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4537065/ https://ncbi.nlm.nih.gov/pubmed/25662282 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503757h |
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