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10 Step Asymmetric Total Synthesis and Stereochemistry of (+)-Dragmacidin D
The asymmetric synthesis of dragmacidin D (1) has been completed in 10 steps. Its sole stereocenter was set using direct asymmetric alkylation enabled by a C(2)-symmetric tetramine and lithium N-(trimethylsilyl)-tert-butylamide as the enolization reagent. A central Larock indole synthesis was employ...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4532559/ https://ncbi.nlm.nih.gov/pubmed/26130270 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504113 |
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