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Total Synthesis of (±)–Dragmacidin E: Problems Solved and Lessons Learned
(±)–Dragmacidin E was synthesized in 25 steps from commercially available 7-(benzyloxy)indole. Key transformations in this sponge metabolite’s preparation include (a) a Witkop cyclization to establish the bridging indole core, (b) cyclo-dehydrative pyrazinone formation to unite the two indole-bearin...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3779142/ https://ncbi.nlm.nih.gov/pubmed/24058268 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0031-1290692 |
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