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Synthetic Strategies Toward the Decalin Motif of Maklamicin and Related Spirotetronates
Herein we describe a scalable approach to the decalin moiety of maklamicin. Key to the synthesis is an intramolecular Diels-Alder (IMDA) reaction that proceeds via an endo-axial transition state to generate the desired stereochemistry. We explored the diastereoselectivity of the IMDA reaction as a f...
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| Publicado no: | Org Chem Front |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4527581/ https://ncbi.nlm.nih.gov/pubmed/26257916 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4QO00332B |
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