Sulfoxide-Directed Metal-Free ortho-Propargylation of Aromatics and Heteroaromatics

A sulfoxide-directed, metal-free ortho-propargylation of aromatics and heteroaromatics exploits intermolecular delivery of a propargyl nucleophile to sulfur followed by an intramolecular relay to carbon. The operationally simple cross-coupling procedure is general, regiospecific with regard to the p...

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Pubblicato in:Chemistry
Autori principali: Eberhart, Andrew J, Shrives, Harry J, Álvarez, Estela, Carrër, Amandine, Zhang, Yuntong, Procter, David J
Natura: Artigo
Lingua:Inglês
Pubblicazione: WILEY-VCH Verlag 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4524421/
https://ncbi.nlm.nih.gov/pubmed/25752800
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201406424
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