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Reduction of CO(2) by pyridine monoimine molybdenum carbonyl complexes: Cooperative metal-ligand binding of CO(2)

(Ar)PMI-Mo(CO)(4) complexes (PMI = pyridine monoimine; Ar = Ph, 2,6-di-iso-propylphenyl) were synthesized and their electrochemical properties were probed with cyclic voltammetry and infrared spectroelectrochemistry (IR-SEC). The complexes exhibit a reduction at more positive potentials than the rel...

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Pubblicato in:Chemistry
Autori principali: Sieh, Daniel, Lacy, David C., Peters, Jonas C., Kubiak, Clifford P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4523092/
https://ncbi.nlm.nih.gov/pubmed/25924730
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201500463
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