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Differential Reduction of CO(2) by Molybdenum and Vanadium Nitrogenases

The Mo- and V-nitrogenases are two homologous enzymes with distinct structural and catalytic features. Previously, we demonstrated that the V-nitrogenase was nearly 700 times more active than its Mo-counterpart in reducing CO to hydrocarbons. Here, we report a similar discrepancy between the two nit...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Rebelein, Johannes G., Hu, Yilin, Ribbe, Markus W.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4240507/
https://ncbi.nlm.nih.gov/pubmed/25205285
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201406863
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