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Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases
Vanadium-dependent nitrogenase was previously shown in a small-scale reaction to catalyze reductive catenation of CO to C(2)H(4), C(2)H(6), C(3)H(6) and C(3)H(8). Here, we report the identification of additional hydrocarbon products, α-C(4)H(8), n-C(4)H(10) and CH(4), in a scaled-up reaction featuri...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2011
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3153399/ https://ncbi.nlm.nih.gov/pubmed/21817053 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1206883 |
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