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(13)C and (63,65)Cu ENDOR studies of CO dehydrogenase from Oligotropha carboxidovorans. Experimental evidence in support of a copper-carbonyl intermediate

We report here an ENDOR study of an S = ½ intermediate state trapped during reduction of the binuclear Mo/Cu enzyme CO dehydrogenase by CO. ENDOR spectra of this state confirm that the (63,65)Cu exhibits strong and almost entirely isotropic coupling, show that this coupling atypically has a positive...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Shanmugam, Muralidharan, Wilcoxen, Jarett, Habel-Rodriguez, Diana, Cutsail, George E., Kirk, Martin L., Hoffman, Brian M., Hille, Russ
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4521601/
https://ncbi.nlm.nih.gov/pubmed/24147852
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406136f
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