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(13)C and (63,65)Cu ENDOR studies of CO dehydrogenase from Oligotropha carboxidovorans. Experimental evidence in support of a copper-carbonyl intermediate
We report here an ENDOR study of an S = ½ intermediate state trapped during reduction of the binuclear Mo/Cu enzyme CO dehydrogenase by CO. ENDOR spectra of this state confirm that the (63,65)Cu exhibits strong and almost entirely isotropic coupling, show that this coupling atypically has a positive...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4521601/ https://ncbi.nlm.nih.gov/pubmed/24147852 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406136f |
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