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The Hydrogenase Activity of the Molybdenum/Copper-containing Carbon Monoxide Dehydrogenase of Oligotropha carboxidovorans

The reaction of the air-tolerant CO dehydrogenase from Oligotropha carboxidovorans with H(2) has been examined. Like the Ni-Fe CO dehydrogenase, the enzyme can be reduced by H(2) with a limiting rate constant of 5.3 s(−1) and a dissociation constant K(d) of 525 μm; both k(red) and k(red)/K(d), refle...

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Autors principals: Wilcoxen, Jarett, Hille, Russ
Format: Artigo
Idioma:Inglês
Publicat: American Society for Biochemistry and Molecular Biology 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3861653/
https://ncbi.nlm.nih.gov/pubmed/24165123
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M113.522441
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