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Characterizing Pressure-Induced Uranium C=H Agostic Bonds**
The diuranium(III) compound [UN′′(2)](2)(μ-η(6):η(6)-C(6)H(6)) (N′′=N(SiMe(3))(2)) has been studied using variable, high-pressure single-crystal X-ray crystallography, and density functional theory. In this compound, the low-coordinate metal cations are coupled through π- and δ-symmetric arene overl...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
WILEY-VCH Verlag
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4515102/ https://ncbi.nlm.nih.gov/pubmed/25882329 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201411250 |
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