Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin**

Dodecaborate anions of the type B(12)X(12)(2−) and B(12)X(11)Y(2−) (X=H, Cl, Br, I and Y=OH, SH, NH(3)(+), NR(3)(+)) form strong (K(a) up to 10(6) L mol(−1), for B(12)Br(12)(2−)) inclusion complexes with γ-cyclodextrin (γ-CD). The micromolar affinities reached are the highest known for this native C...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Assaf, Khaleel I, Ural, Merve S, Pan, Fangfang, Georgiev, Tony, Simova, Svetlana, Rissanen, Kari, Gabel, Detlef, Nau, Werner M
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4510780/
https://ncbi.nlm.nih.gov/pubmed/25951349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201412485
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